I would like to know the rules for new users?

Would like to ask as a new user how to post successfully? How can I unblock new users?

I’m not sure I understand the question here. You have successfully posted.

Also, if a new user is blocked for some reason (usually because of posting too fast - generally caused by copy/pasting the body of their post from a different source), the moderators get notified and will review / approve the post as appropriate.